Characterization of oligomeric compounds in secondary organic aerosol using liquid chromatography coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry.

Interactive comment on “Molecular characterization of aerosol-derived water soluble organic carbon using ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry” by A. S. Wozniak et al

Study of a complex environmental mixture by electrospray ionization and laser desorption ionization high resolution mass spectrometry: the cigarette smoke aerosol

Aerosols from the mainstream cigarette smoke have been analyzed by electrospray ionization (ESI) coupled to Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). Measurements have been conducted in positive ion mode. The chemical composition of cigarette smoke aerosol is significant because it gives insights of one complex indoor environmental mixture. Almost 1300 chemical comp...

Molecular Characterization of Organosulfur Compounds in Biodiesel and Diesel Fuel Secondary Organic Aerosol.

Secondary organic aerosol (SOA), formed in the photooxidation of diesel fuel, biodiesel fuel, and 20% biodiesel fuel/80% diesel fuel mixture, are prepared under high-NOx conditions in the presence and absence of sulfur dioxide (SO2), ammonia (NH3), and relative humidity (RH). The composition of condensed-phase organic compounds in SOA is measured using several complementary techniques including...

Technical Note: Molecular Characterization of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

Despite the acknowledged relevance of aerosolderived water-soluble organic carbon (WSOC) to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) was utilized in this study to provide detailed molecular level characterization of the high molecular weight (HMW; m/z...

High-resolution Fourier transform ion cyclotron resonance mass spectrometry of humic and fulvic acids: improvements and comparisons.

Full structural characterization of complex mixtures such as humic acid extracts has been elusive because of insufficient compound resolution with conventional techniques. Using electrospray ionization coupled with Fourier transform ion cyclotron resonance mass spectrometry, we were able to resolve individual compounds within humic and fulvic acid mixtures (mass resolving power approximately 80...